Unveiling the World of Cosmetic Colour Ingredients

Imagine a world devoid of cosmetic colour. No vibrant red lipstick, no striking blue eyeshadow, no soft pink blushes – just a monochrome existence. In the realm of cosmetics, colourants play a crucial role in transforming and differentiating products. These hues aren’t just random pigments thrown into a mix; they’re intricate compounds that incorporate physics, chemistry, and even biology to create a visual message. Join us as we delve into the mesmerizing world of cosmetic colour ingredients, exploring the types, creation processes, regulations, and everything in between.

Colourants 101

When you admire a lipstick shade or a shimmering eyeshadow, you’re appreciating the artistry of colourants. In the cosmetic realm, colourants are substances exclusively designed to add vibrant hues to products and enhance the human body’s visual appeal. These colours come to life through the absorption and reflection of visible light – a phenomenon blending science and aesthetics. Pigments are used both to colour the product to make it attractive to the consumer or to colour the body.

Two primary categories define cosmetic colourants: dyes and pigments. Dyes dissolve into product bases like water, oil, or alcohol. The synthetic versions often reign supreme due to their intense colour potency, outshining natural alternatives.

The other type is pigments, which are insoluble in their product base. They offer robust and long-lasting colour. The pigments themselves can be further categorized into organic and inorganic variants. There are very few true organic pigments; most are made by precipitation onto another substance to make a Lake.

A Lake is produced when a soluble dye is reacted with a metal ion which converts it into an insoluble substance. Note the INCI name for a Lake is exactly the same as the INCI name of the dye e.g. Yellow 5 Aluminium Lake has INCI name CI 19140, and is also used for the soluble dye Yellow 5. Although the INCI name / CI number is the same, there can be differences in the toxicity profile, and therefore the safety assessment has to reflect which one was used.

In the world of inorganic pigments, iron oxides (such as CI 77491, CI 77492, and CI 77499) are commonplace, contributing earthy hues. Another intriguing example is CI 77007, a label encompassing a family of Ultramarines, which span shades from azure to violet. Understanding these colourant types is pivotal, as they’re central to the cosmetic industry’s creative palette.

Regulations: The Colourful Landscape of Compliance

Navigating the world of colourants isn’t without its regulatory complexities. Annex IV of the Cosmetic Regulation is the compass that guides permissible colourant use in cosmetic products. Any pigmented ingredient absent from this annex can’t be employed solely for colouring purposes. However, if such an ingredient serves another function, it’s not bound by this restriction. The CosIng database is a trove of information regarding ingredient functions, guiding formulators through this intricate tapestry of colour.

Change is inevitable, and even colourants are subject to evolving standards. The process of amending annex entries necessitates careful consideration, involving reviews and commentary periods. A classic example is CI 77891 (Titanium Dioxide), an ingredient with numerous updates over time. It’s essential for suppliers to provide current documentation confirming purity compliance, ensuring the safety and quality of cosmetic products to the most current standards.

After Brexit, the UK adopted the entirety of the EU Annex, but over time, it is possible that there will be divergence from the original Annex entries. Up to now there has not been significant divergence and CPSRs produced by GCS comply with both jurisdictions.

Decoding INCI Names: The Language of Colour Ingredients

The world of colourants has its own language, and INCI names are its vocabulary. Most colourants adhere to the CI nnnnn format, where CI signifies Colour Index followed by a five-digit number. While Mica has a CI number (CI 77019), its official INCI name remains ‘Mica.’ Similarly, Tin Oxide (CI 77861) defies its CI number when it comes to INCI naming.

Notably, a few colourants eschew CI numbers altogether, including Carbon Black, Lactoflavin, Caramel, Capsanthin (derived from paprika extract), Beetroot Red, Anthocyanins, Aluminium Stearate, Zinc Stearate, Magnesium Stearate, Calcium Stearate, Bromothymol Blue, Bromocresol Green, and Acid Red 195.

Labelling Colours: Label Ingredient Listing

The Cosmetic Regulation allows decorative cosmetic products like eyeshadows, blushes, and foundations to list all colourants within the range. These listings require the use of ‘may contain’ or the +/- symbol, showcasing the range of hues that are within.

The Alchemy of Colour Creation: Manufacture of Pigments and Dyes

Some colours are mined, such as iron oxides, titanium dioxide, and mica. Yet, mining isn’t without its challenges, as heavy metal contamination can occur. Rigorous processing and testing transform these raw materials into cosmetic-grade raw materials, ensuring their safety and purity. If your colourant is unexpectedly cheap, this may be because it is not cosmetic-grade material.

Synthetic dyes, on the other hand, undergo chemical synthesis, resulting in highly pure, vibrant colours. The EU Cosmetic Regulation often aligns with food purity requirements, characterized by E-numbers for identification. The United States, history marred by colourant safety issues, upholds stringent regulations. The colourant is named with a FD&C (Food, Drug And Cosmetic) or D&C (Drug & Cosmetic) number and each batch produced has to be traceable back to the source.

During manufacture, colourants may contain impurities or processing aids (often listed on the Safety Data Sheet). These, however, don’t necessitate listing in the INCI name, as they are not intentional additions.

Pearlescence: The Mica Magic

For a pearlescent look, mica reigns supreme. Pigments are layered on top of mica bases, and the possibilities are endless. Titanium dioxide coated onto mica plates at various thicknesses provides a spectrum of effects and colours. Additional pigments further expand the colour horizon, offering an array of choices. There are also mica substitutes available such as Synthetic Fluorphlogopite and Calcium Aluminium Borosilicate.

Challenges and Triumphs: Unveiling the Beauty of Colours

Some hues may fade under sunlight, a concern addressed through UV-absorbing additives or opaque packaging. Natural dyes occasionally carry an odour, necessitating the use of masking scents. Microplastic glitter, once ubiquitous, now bows to the rise of biodegradable ‘bio-glitters,’ embodying beauty and environmental responsibility. Glitter used to be made using coated sheets of a polymer such as polyethylene, which is then chopped into extremely small pieces to provide different grades and sizes of glitter. The bio-glitters use a biodegradable base structure onto which pigments are coated.

Particle size variation can present another issue, with some colourants defined within the nanoparticle classification. Carbon black, titanium dioxide, and zinc oxide, while often used as UV filters, possibly fall into this category. Suppliers’ documents are vital for clarifying particle sizing.

Purity: The Essence of Compliance

Purity requirements underpin colourant safety. Compliance with Annex purity criteria rests on suppliers’ shoulders, as intricate supply chains lead to trickly verification. Notably, the US FDA and EU/UK set distinct limits, with permitted colours differing between the regions.

There are many colours that are listed for-rinse-off use only, and therefore cannot be used in any product that is for leave-on usage. Another subset is for colours which should not be used in products applied to the mucous membranes (eyes, oral, genital), or are not permitted for use in eye products specifically. Some also have maximum amounts permitted for use.